朱大建

基于傅-克、共缩聚等方法将具有配位功能的分子构建于聚合物骨架上，负载金属催化剂用于催化交叉偶联、C−H键活化等反应，研究制备方法、单体种类、配体种类、载体结构、孔径大小等对反应性能的影响，探索多相催化的构效关系。

研究领域及兴趣

[1] C−H键活化

[2] 多相催化

承担项目与课题

基于C−H键活化合成双氯芬酸钠的新方法研究（湖北省自然科学基金，2016-2017）

催化合成双氯灭痛的新方法研究（催化材料科学湖北省暨国家民委－教育部共建      重点实验室开放基金，2015-2017）

基于C−H键活化合成含C−N键药物分子的新方法研究（深圳市科技计划项目，2015-2017）

钯催化C(sp²)−H键胺化反应构建C−N键功能分子的研究（18luck新利电竞 自主创新基金，2015-2016）

基于Kolbe-Schmitt反应的二氧化碳资源化利用研究（18luck新利电竞 自主创新基金，2012-2013）

钴配合物催化氧化羰化法合成碳酸甘油酯的研究（湖北省自然科学基金，2011-2012）

代表性成果

[1] Yahao Dong, Jiajun Bi, Dajian Zhu, Di Meng, Shujun Ming, Wen Guo, Zhen Chen, Qian Liu, Lei Guo, Tao Li, Functionalized cellulose with multiple binding sites for a palladium complex catalyst: synthesis and catalyst evaluation in Suzuki–Miyaura reactions, Cellulose, 2019, 26:7355-7370.

[2] Jiajun Bi, Yahao Dong, Dajian Zhu, Wen Guo, Di Meng, Tao Li,⁎PdxCuy decorate hypercrosslinked network: Synthesis and application as efficient catalysts for the reduction of 4-nitrophenol and Suzuki-Miyaura coupling reaction, Applied Surface Science, 2019, 49, 143584.

[3] Jian Chen, Ju Zhang, Dajian Zhu*, Tao Li*, Porphyrin-based polymer-supported Pd as an excellent and recyclable catalyst for Suzuki-Miyaura coupling reaction in water, Appl. Organometal. Chem., 2018, DOI: 10.1002/aoc.3996. 

[4] Jian Chen, Ju Zhang, Weiting Sun, Kunpeng Song, Dajian Zhu*, Tao Li*, Pd immobilized on polyamide based on melamine and terephalic acid as an efficient and recyclable catalyst for Suzuki-Miyaura coupling reaction, Appl. Organometal. Chem., 2018, DOI: 10.1002/aoc.4135. 

[5] Jian Chen, Ju Zhang, Dajian Zhu*, Tao Li*, Novel polymer-supported phosphine palladium catalyst: one-pot synthesis from and application in Suzuki-Miyaura coupling reaction, J. Porous Mater., 2017, 24(4), 847. DOI:10.1007/s10934-016-0324-7. 

[6] Guoqiang Yang, Dajian Zhu, Peng Wang, Ri-Yuan Tang and Jin-Quan Yu*, Remote C-H Activation of Various N-Heterocycles Using a Single Template, Chem. Eur. J. 2018, 24, 3434. https://doi.org/10.1002/chem.201800105. 

[7] Dajian Zhu, Guoqiang Yang, Jian He, Ling Chu, Gang Chen, Wei Gong, Ke Chen, Martin D. Eastgate and Jin-Quan Yu*, Ligand-Promoted ortho-C-H Amination with Pd Catalysts, Angew. Chem. Int. Ed. 2015, 54, 2497. https://doi.org/10.1002/anie.201408651.

[8] Guoqiang Yang, Petra Lindovska, Dajian Zhu, Justin Kim, Peng Wang, Ri-Yuan Tang, Mohammad Movassaghi, Jin-Quan Yu*, Pd(II)-catalyzed meta-C–H olefination, arylation, and acetoxylation of indolines using a U-shaped template, J. Am. Chem. Soc., 2014, 136, 10807. dx.doi.org/10.1021/ja505737x.  

[9] Dajian Zhu, Fuming Mei, Lijuan Chen, Wanling Mo, Tao Li, Guangxing Li*, An efficient catalyst Co(salophen) for synthesis of diethyl carbonate by oxidative carbonylation of bio-ethanol, Fuel, 2011, 90, 2098. DOI:10.1016/j.fuel.2011.02.023.  

[10] Dajian Zhu, Fuming Mei, Lijuan Chen, Tao Li, Wanling Mo, and Guangxing Li*, Synthesis of dimethyl carbonate by oxidative carbonylation using an efficient and recyclable catalyst Co-Schiff base/zeolite, Energy & Fuels, 2009, 23, 2359. DOI:10.1021/ef801115e.

发明专利

1. 一种双氯芬酸甲酯的合成方法

申请号：201711184387.0

申请（专利权）人：18luck新利电竞

发明人：朱大建，李涛，陈建，毕佳俊，孟迪

2. 一种双氯芬酸钠的合成方法

申请号：201711184410.6

申请（专利权）人：深圳18luck新利电竞 研究院

发明人：朱大建